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P.H
Welcome to this webpage we will be talking about P.H
The balance of positive hydrogen ions (H+) and negative
hydroxide ions (OH-) in water determines how acidic or basic the water is. Notice
the ' + ' and ' - ' in the chemical symbols above. They indicate that these
chemical forms are 'ions' — they have a positive or negative electrical
charge. This means the molecule in question is either missing an electron or
has an extra electron. Since electrons have a negative charge, an extra one
in the OH molecule makes it OH-, and a missing one in the H molecule gives it
a "missing-minus" charge — in other words, positive —
and makes it H+. When analysts measure pH, they are determining the balance
between these ions.
(cool h2ou student tip: to remember what pH is, think of the term "pH"
as positive Hydrogen).
The pH scale ranges from 0 (high concentration of positive hydrogen ions, strongly
acidic) to 14 (high concentration of negative hydroxide ions, strongly basic).
In pure water, the concentration of positive hydrogen ions is in equilibrium
with the concentration of negative hydroxide ions, and the pH measures exactly
7.
In a lake or pond, the water’s pH is affected by its age and the chemicals
discharged by communities and industries. Most lakes are basic (alkaline) when
they are first formed and become more acidic with time due to the build-up of
organic materials. As organic substances decay, carbon dioxide (CO2) forms and
combines with water to produce a weak acid, called "carbonic" acid
— the same stuff that’s in carbonated soft drinks. Large amounts
of carbonic acid lower water’s pH.
Most fish can tolerate pH values of about 5.0 to 9.0, but serious anglers look
for waters between pH 6.5 and 8.2. The vast majority of American rivers, lakes
and streams fall within this range, though acid rain has compromised many bodies
of water in our environment.
Synergistic Effects of pH
Synergy is the process whereby two or more substances combine and produce effects
greater than their sum. For example, 2 + 2 = 4 (mathematically). But synergistically,
2 + 2 = much more than 4! Synergy is a mathematical impossibility, but it is
a chemical reality. Here’s how it works:
When acid waters (waters with low pH values) come into contact with certain
chemicals and metals, they often make them more toxic than normal. As an example,
fish that usually withstand pH values as low as 4.8 will die at pH 5.5 if the
water contains 0.9 mg/L of iron. Mix an acid water environment with small amounts
of aluminum, lead or mercury, and you have a similar problem—one far exceeding
the usual dangers of these substances.
The pH of sea (salt) water is not as vulnerable as fresh water’s pH to
acid wastes. This is because the different salts in sea water tend to buffer
the water with Alka-Seltzer-like ingredients. Normal pH values in sea water
are about 8.1 at the surface and decrease to about 7.7 in deep water. Many shellfish
and algae are more sensitive than fish to large changes in pH, so they need
the sea’s relatively stable pH environment to survive.
Shallow waters in subtropical regions that hold considerable organic matter
often vary from pH 9.5 in the daytime to pH 7.3 at night. Organisms living in
these waters are able to tolerate these extremes or swim into more neutral waters
when the range exceeds their tolerance.